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Polarization switching and inversion in external stimuli-responsive non-ferroelectric Cobalt-dioxolane molecular systems for energy harvesting prospects

Implementing Organization

Principal Investigator
Dr. Pritam sadhukhan
Department of Condensed Matter Physics and Materials Science, SN Bose Natioanl Centre for Basic Sciences, Kolkata, West Bengal, 700098
Indian Association for the Cultivation of science

About

Modern information technology has led to a growing interest in polar materials, particularly ferroelectric materials, due to their stimuli-responsive properties. However, conventional ferroelectric materials face challenges in polarization, as they require collective lattice modes to construct low-symmetry ferroelectric and high-symmetry paraelectric phases. Dynamic molecular crystals with molecular tailorability can switch electronic, magnetic, and optical properties by external stimuli. Cobalt-dioxolene Valence Tautomeric (VT) complexes are ideal candidates for this purpose, as they show intramolecular electron transfer and can be manipulated by external perturbations like heat, light, pressure, and magnetic fields. Light-induced polarization switching is considered more energy-efficient and could be used for high-speed switching in the quantum optoelectronics industry. Magnetic field switching in multiferroic materials is a popular topic in condensed matter physics, and researchers are exploring the possibility of achieving the magnetoelectric effect in molecular magnetic materials without long-range ordering features. This approach also allows for stimuli-responsive inversion of polarization direction, which is currently only realized in ferroelectric systems with an external electric field.

Source

Source
science and Engineering Research Board (sERB), DsT
Funding Organization
Funding Organization
Anusandhan National Research Foundation (ANRF)
Quick Information
Area of Research
Chemical Sciences
Focus Area
Nanotechnology, Energy science
Start Year
2024
End Year
2026
Status
Ongoing
Contact
pritamchemistry1994@gmail.com
Output
No. of Research Paper
00
Technologies (If Any)
00
No. of PhD Produced
00
No. of Patents
Filed : 00
Grant : 00
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