Understanding the role of self-assembly of nanoparticles in tailoring the thermal conductivity of nanofluids using in-situ liquid phase electron microscopy
Implementing Organization
Institute of Technology (IIT) Mandi, Himachal Pradesh
Principal Investigator
Dr. Sarthak Nag
Institute of Technology (IIT) Mandi, Himachal Pradesh
Project Overview
Nanofluids are liquid suspensions with nanoparticles with diameters ranging from 1 to 100 nanometers, which are essential for their enhanced thermal conductivity. However, no models have been able to predict the thermal conductivity of all nanofluids, indicating a lack of understanding of heat transport in nanofluids at molecular-level scales. Self-assembly, or aggregation of nanoparticles, can modify the thermal conductivity of nanofluids through various mechanisms. When dispersed in a fluid, nanoparticles tend to agglomerate due to attractive forces, limiting the effective surface area available for heat transfer. However, self-assembly can also lead to stable structures, such as long-chains, networks, or layers of nanoparticles, which can create more effective heat transfer pathways. This study aims to establish the correlation between self-assembly in nanofluids and thermal conductivity by investigating factors affecting nanoparticle self-assembly and the role of ordered structures on the thermal conductivity of nanofluids. The major challenge is the direct observation of nanoparticle self-assembly due to their nanometre length scales. In-situ liquid phase electron microscopy will be applied, where nanofluids will be encapsulated between electron-translucent 2D material (graphene or SiNx) and observed using a transmission electron microscope. The thermal conductivity of these nanofluids will be tested in an in-house developed thermal conductivity measurement setup. This research will deepen our understanding of the relationship between self-assembly and thermal conductivity in nanofluids, providing guidance for the rational design of high-performance nanofluids for practical applications in energy and heat transfer industries. The results will also be useful in designing and optimizing nanofluids for heat transfer applications.