Synergistic Advancements in Li-S Batteries: Unveiling Monoclinic Sulfur for Stable, Prolong Cycling and Superior Performance
Implementing Organization
Jawaharlal Nehru University
Principal Investigator
Dr. Puspendra Kumar
Jawaharlal Nehru University
Project Overview
The global interest in alternative energy sources, particularly rechargeable batteries, is growing due to their potential applications in portable consumer electronics and electric vehicles. However, the current Li-ion batteries have limited storage capacity due to their structure and electrode materials, making them insufficient for EVs and grid storage. The demand for a more powerful energy storage system is increasing, and lithium-sulfur (Li-S) is considered the most promising next-generation high-energy storage system. Li-S batteries can store more than five times more energy theoretically than conventional LIBs. However, challenges such as preventing sulfur/polysulfide dissolution in the electrolyte, controlling Li metal amounts to improve safety and reduce costs, and suppressing lithium dendrite growth are necessary for commercialization. The proposed Li-S battery aims to develop a safer and sustainable Li-S battery that can deliver high energy density, extended cycle life, and reduced costs. The improvement focuses on encapsulating/ accommodating/ anchoring and stabilizing the sulfur allotrope (gamma sulfur), which reduces polysulfide dissolution. Using suitable conducting hosts like porous graphene, activated carbons, metal or metal oxides decorated graphene/graphene oxide, and polymer PAN fiber, the proposed Li-S battery has a fair chance of dominating the energy market and potentially replacing traditional Li-ion batteries.