Non-innocent Redox-active Ligand Assisted Transition Metal-Catalysed Organic Transformations, Cross-Couplings and Hydrogen Evolution Reactions with Mechanistic Insight
Implementing Organization
University of North Bengal
Principal Investigator
Dr. Hari sankar Das
University of North Bengal
About
Visible light-driven photoredox catalysis is gaining attention for efficient organic transformations under mild conditions. Active transition metals facilitate single electron transfer processes, producing reactive charged radical intermediates. scientists are focusing on visible light-mediated metal catalyzed cross-coupling reactions due to their eco-friendly and green nature. Recent reports on C-C and C-N coupling reactions have been addressed, but C-s and C-O coupling reactions are less reported. To overcome sustainability and scalability issues, inexpensive organic dyes have been introduced in metal catalytic processes. This project proposes designing and synthesizing metal catalytic systems with suitable ligands, such as dithioether (1,2 or 1,3) moiety, for photoluminescence metal coordination polymer complexes. The dithioether ligands and their metal coordination polymers will be characterized using various spectroscopic techniques, and their photoluminescence properties will be examined. The metal-CPs will then be applied in visible light-mediated cross coupling reactions under ambient conditions.
Source
Source
Anusandhan National Research Foundation/science and Engineering Research Board (sERB), DsT 2023-24
Science and Engineering Research Board (SERB), New Delhi
Anusandhan National Research Foundation (ANRF)
Quick Information
Area of Research
Chemical Sciences
Start Year
2024
End Year
2027
Sanction Amount
₹ 39.65 L
Status
Ongoing
Contact
haridasiitk@gmail.com
Output
No. of Research Paper
00
Technologies (If Any)
00
No. of PhD Produced
00
No. of Patents
Filed :00
Grant :00
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