Developing diamond coatings on high cobalt content WC-10%Co substrates for machining applications
Implementing Organization
National Institute of Technology Calicut
Principal Investigator
Dr. Maneesh Chandran
National Institute of Technology Calicut
CO-Principal Investigator
Dr. Basil Kuriachen
National Institute of Technology Calicut
Project Overview
Diamond, the hardest known material, is not suitable for fabricating machining tools due to its poor chip resistance. However, cemented tungsten carbide (WC-Co) has high fracture toughness and is commonly used for manufacturing machining tools. By depositing a thin layer of CVD diamond coating on WC-Co substrate, the hardness of diamond can be combined with WC-Co's toughness. However, poor adhesion leads to a lesser lifetime for the diamond-coated tools. Realizing adherent diamond coatings on WC-Co substrates has always been a challenge, as it requires eliminating carbon-cobalt interactions during the diamond deposition process. The conventional chemical etching method is not feasible for high cobalt content WC-Co substrates. The current industrial trend is to increase cobalt content above 8% to improve the toughness of machining tools. The proposed research aims to develop novel, graded layer diamond coatings, along with a CrN interlayer, to realize adherent diamond coatings on high cobalt content WC-10%Co inserts for machining applications. The CrN layer acts as a diffusion barrier, providing improved chemical and mechanical adhesion to both diamond films and WC-Co substrates. Adopting a graded NCD/MCD coating methodology will exploit the advantages of both MCD and NCD layers, improving adhesion. The potential of diamond-coated WC-10%Co inserts with a CrN interlayer will be demonstrated by machining Al-si alloy and comparing results with commercially available hard coating tools. This research has significant economic impact, as the global hard coatings market is valued at 1 billion UsD and projected to reach 1.4 billion UsD by 2026.