"Development of tunable p-n heterojunctions for gas sensing and photocatalytic applications"
Implementing Organization
Osmania University
Principal Investigator
Dr. Gangadharini Upender
Osmania University
Project Overview
Photocatalytic visible active materials are crucial for environmental remediation, especially with the abundant solar energy. Composites with p-n heterojunctions are more effective than single phase composites for maximum photocatalytic activity (PCA). The study aims to explore the performance of p-n heterojunctions for various dyes and gas sensing responses at different temperatures. The research will involve 12 series of p-n heterojunctions synthesized using the hydrothermal method. Experiments will be conducted to identify phases, micro-structures, nano-structure, elemental analysis, oxidation states, optical band gap estimation, partial density of states (PDOs), functional groups, surface area measurement, photo-degradation studies, photoluminescence recording, scanning electron microscopy, mott-schottky and Nyquist plots, and gas sensing studies of thin film-coated samples. Various techniques will be used to analyze the phases, micro-structures, and nano-structure of the composites. XRD, FEsEM, TEM, EDX, XPs, UV-Vis-DRs analysis, DFT, FTIR, Raman spectroscopies, and BET techniques will be used to analyze the samples. Photo-degradation studies will be conducted under sun-light/visible light, photoluminescence will be recorded, and scavenger tests will be conducted to confirm the roles of various radicals in dye degradation. Mott-schottky and Nyquist plots will be measured to study p-n junction characteristics, and gas sensing studies will be conducted on thin film-coated samples. The studies conducted on these series may provide a scientific advancement in terms of plausible mechanisms for gas sensing and PCA.